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An important target of Cu I toxicity is the FeS cluster biogenesis machinery, 165167 as well as FeS clusters of mature enzymes, including dehydratases, where Cu I displaces one or more Fe atoms on what are essentially solvent exposed clusters, 168 potentiating oxidative stress through Fenton chemistry
BPC 157 enhances function of immunological effector cells in mice
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While the impact of Cu regulation on the crosstalk between Zn and Mn has been investigated in other CopY-encoding bacteria, 176 it remains unclear whether the mechanistic proposal described for Sp CopY characterizes other members of this group of repressors
